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Synthesis of reduced graphene oxide/NiO nanocomposites for the removal of Cr(VI) from aqueous water by adsorption |
论文题目:
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Synthesis of reduced graphene oxide/NiO nanocomposites for the removal of Cr(VI) from aqueous water by adsorption
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英文论文题目:
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Synthesis of reduced graphene oxide/NiO nanocomposites for the removal of Cr(VI) from aqueous water by adsorption
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第一作者:
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张可心
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英文第一作者:
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Zhang, K. X.
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联系作者:
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于洪文
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英文联系作者:
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Yu, H. W.
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发表年度:
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2018
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卷:
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225
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页码:
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7-14
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摘要:
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In this work, we report a room-temperature approach to synthesizing reduced graphene oxidei/NiO (RGO/NiO) nanocomposites. The chemical structure of RGO/NiO nanocomposites were investigated by Transmission Electron Microscope (TEM), X-ray photoelectron spectroscopy (XPS), and X-ray power diffraction (XRD). It is shown by the experiment that the RGO/NiO nanocomposites have strong capacity to absorb the hexavalent chromium ion (Cr (VI)), the maximum adsorption capacity of Cr (VI) on RGO/NiO nanocomposites at pH = 4 and T = 25 degrees C can reach 198 mg g(-1), higher than any other currently reported. The adsorption kinetic data were well described by a pseudo-second-order model. Both Freundlich and Langmuir isotherm models were applied to the experimental data analysis, and the latter proved to be a better fit. The pH value markedly affected the adsorption behavior of RGO/NiO nano composites, but the effect of temperature was insignificant. The probable mechanism of synergistic adsorption of Cr (VI) ions was considered. These results suggest that RGO/NiO nanocomposites have the potential to be applied in industrial wastewater treatment. (C) 2017 Elsevier Inc. All rights reserved.
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刊物名称:
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Microporous and Mesoporous Materials
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英文刊物名称:
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Microporous and Mesoporous Materials
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参与作者:
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Li, H. Y.,Xu, X. J.,Yu, H. W.
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